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Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
8 steps
Depiction
Dead-End Product
Carbonic Acid
C(=O)(O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
7 steps
Depiction
Dead-End Product
Oxalic Acid
C(=O)(C(O)=O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
11 steps
Depiction
Dead-End Product
Methanediol
C(O)O
Depiction
Upstream Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carbaldehyde
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C=O)OC
Depth 1
Depiction
Product
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depiction
Upstream Precursor
[(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthren-3-yl]methanol
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)CO)OC
Depth 2
Depiction
Product
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 2
Depiction
Downstream Successor
(+)-Totarol
CC(C)c1c(ccc2c1CCC3C2(CCCC3(C)C)C)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 3
Depiction
Downstream Successor
7-hydroxy-1,1,4a-trimethyl-8-propan-2-yl-3,4,10,10a-tetrahydro-2H-phenanthren-9-one
CC(C)C1=C(C=CC2=C1C(CC3C2(CCCC3(C)C)C)=O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 3
Depiction
Downstream Successor
14-Isopropylpodocarpa-8,11,13-triene-7,13-diol
C1(CC2C(CCCC2(C)C)(C3=C1C(=C(C=C3)O)C(C)C)C)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 2
Depiction
Downstream Successor
(4bS,8aS)-1-isopropyl-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-2,3-diol
CC(C)c1c(c(cc2c1CCC3C2(CCCC3(C)C)C)O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 3
Depiction
Downstream Successor
CC(C)c1c(cc(c2c1CCC3C2(CCCC3(C)C)C)O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 2
Depiction
Downstream Successor
CC(C)C(=C1C(=CC(O)=O)C2(C(CC1)C(CCC2)(C)C)C)C(=O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 3
Depiction
Downstream Successor
6,7-dihydroxy-1,1,4a-trimethyl-8-propan-2-yl-3,4,10,10a-tetrahydro-2H-phenanthren-9-one
CC(C)c1c(c(cc2c1C(CC3C2(CCCC3(C)C)C)=O)O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 3
Depiction
Downstream Successor
CC(C)C(=C1C(=CC(O)=O)C2(C(CC1O)C(CCC2)(C)C)C)C(=O)O
Depiction
Precursor
(4bS,8aS)-1-isopropyl-2-methoxy-4b,8,8-trimethyl-5,6,7,8a,9,10-hexahydrophenanthrene-3-carboxylic acid
CC(C)C1=C(C(=CC2=C1CC[C@@H]3[C@@]2(CCCC3(C)C)C)C(=O)O)OC
Depth 2
Depiction
Downstream Successor
CC(C)C1=C(C(=C(C2=C1CCC3C2(CCCC3(C)C)C)O)O)O
No Original Precursors

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